A University of Central Florida researcher has developed technology that could prevent electric vehicle fires, like those caused by saltwater flooding from Hurricane Ian.
The technology, an aqueous battery, replaces the volatile and highly flammable organic solvents found in EV lithium-ion batteries with saltwater to create a battery that is safer, faster charging, just as powerful and won’t short circuit during flooding.
The work is detailed in a new study, “Three-dimensional Zn-based Alloys for Dendrite-free Aqueous Zn Battery in Dual-cation Electrolytes,” in Nature Communications.
“During Hurricane Ian, a lot of electric cars caught fire after they were soaked in floodwater,” says Yang Yang, an associate professor in UCF’s NanoScience Technology Center who led the research. “That is because the saltwater corrodes the battery and causes a short circuit, which ignites the flammable solvents and other components. Our battery uses saltwater as an electrolyte, eliminating the highly volatile solvents.”
Also key to the battery’s design is its novel, nano-engineering that allows the battery to overcome limitations of previous aqueous batteries, such as slow charging times and poor stability.
The UCF-designed battery is fast-charging, reaching full charge in three minutes, compared to the hours it takes lithium-ion batteries.
Yang is an expert in developing materials for renewable energy devices such as batteries with improved safety.
The issue of electric vehicle fires after saltwater flooding surfaced during Hurricane Sandy in 2012 and Hurricane Isaias in 2020.
As a result, the U.S. Fire Administration and the National Highway Traffic Safety Administration have issued special guidance for responding to electric vehicle fires caused by saltwater flooding.
The fires require copious amounts of water to douse, with the International Association of Fire Chiefs recommending firefighters secure a continuous and sustainable water supply of 3,000 to 8,000 gallons.
At least 12 EV fires were reported in Collier and Lee counties in Florida after Hurricane Ian, where many cars were submerged at least partially in saltwater, according to the US. Fire Administration.
Previous aqueous battery designs have suffered from low energy output, instability, the growth of harmful metallic structures called dendrites on the negative electrode and corrosion.
By using saltwater as the battery’s liquid electrolyte, the UCF researchers were able to use naturally occurring metal ions found in the saltwater, such as sodium, potassium, calcium and magnesium, to create a dual-cation battery that stores more energy. This implementation allowed them to overcome the sluggishness of previous single-cation aqueous battery designs.
To solve problems with instability, dendrite growth and corrosion, the researchers engineered a forest-like 3D zinc-copper anode containing a thin zinc-oxide protective layer on top.
The novel, nano-engineered surface, which looks like a birds-eye-view of a forest, allows the researchers to precisely control electrochemical reactions, thereby increasing the battery’s stability and quick charging ability.
Furthermore, the zinc-oxide layer prevented dendritic growth of zinc, which was confirmed using optical microscopy.
“These batteries using the novel materials developed in my lab will remain safe even if they are used improperly or are flooded in saltwater,” Yang says. “Our work can help improve electric vehicle technology and continue to advance it as reliable and safe form of travel.”
The patent-pending technology is available for licensing through UCF’s Office of Technology Transfer.
The research was supported with funding from the U.S. National Science Foundation and American Chemical Society Petroleum Research Fund.
Yang holds joint appointments in UCF’s NanoScience Technology Center and the Department of Materials Science and Engineering, which is part of the university’s College of Engineering and Computer Science. He is a member of UCF’s Renewable Energy and Chemical Transformation (REACT) Cluster. He also holds a secondary joint-appointment in UCF’s Department of Chemistry and The Stephen W. Hawking Center for Microgravity Research and Education. Before joining UCF in 2015, he was a postdoctoral fellow at Rice University and an Alexander von Humboldt Fellow at the University of Erlangen-Nuremberg in Germany. He received his doctorate in materials science from Tsinghua University in China.